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Nickel-Catalyzed Biaryl Coupling of Heteroarenes and Aryl Halides/Triflates

✍ Scribed by Canivet, Jérôme; Yamaguchi, Junichiro; Ban, Ikuya; Itami, Kenichiro

Book ID
115508438
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
177 KB
Volume
11
Category
Article
ISSN
1523-7060

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✍ Lukas J. Goossen; Christophe Linder; Nuria Rodríguez; Paul P. Lange 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 853 KB

## Abstract A bimetallic catalyst system has been developed that for the first time allows the decarboxylative cross‐coupling of aryl and acyl carboxylates with aryl triflates. In contrast to aryl halides, these electrophiles give rise to non‐coordinating anions as byproducts, which do not interfer