Nickel- and palladium-catalyzed cross-coupling as a route to 1- and 2-alkoxy- or dialkylaminovinylphosphonates
β Scribed by Marina A. Kazankova; Inna G. Trostyanskaya; Serghey V. Lutsenko; Irina P. Beletskaya
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 189 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
An efficient conversion of bis-silylated dienes and trienes into polyenylsilanes by cross-coupling reactions is described. The aryl substituted polyenes are syn~ by ipso.borodesilylation with BCI3 followed by Pd-catalyzed coupling reactions of the resulting boron derivative with aryl halides, wherea
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Scheme 1. Synthesis of conjugated enynes. EWG = electron-withdrawing group, Ts = p-toluenesulfonyl.