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Nickel- and cobalt-plated Raney catalysts


Book ID
104387579
Publisher
Elsevier Science
Year
2008
Weight
54 KB
Volume
2008
Category
Article
ISSN
1351-4180

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The selective reduction of the exocyclic methylene group to produce one stereoisomer is frequently required in the synthesis of terpenoid natural products' 2 or in industrial processes . Homogeneous and heterogeneous hydrogenations of 4-t-butylmethylenecyclohexane3, 4 B-pinene , and 2-methyl.methy

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## Abstract Raney metals were studied as heterogeneous catalysts for racemization and dynamic kinetic resolution (DKR) of chiral amines, as an alternative to metals like palladium or ruthenium. Both Raney nickel and cobalt were able to selectively racemize various chiral amines with high selectivit