A nickel molybdenum phosphate, (NH 3 CH 2 CH 2 NH 3 ) 4 ' (NH 3 CH 2 CH 2 NH 2 ) ' Na ' [Ni 2 Mo 12 O 30 (PO 4 ) (HPO 4 ) 4 (H 2 PO 4 ) 3 ] ' 6H 2 O, involving molybdenum present in V oxidation, has been hydrothermally synthesized and structurally characterized by single crystal X-ray di4raction. De
✦ LIBER ✦
(NH4)2(NH3(CH2)6NH3)4[H2W12O42]·8H2O: a novel ammonium 1,6-hexanediammonium dodecatungstate
✍ Scribed by Gainsford, Graeme J. ;Robinson, Natalie ;Tallon, J. L.
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 399 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
A novel ammonium 1,6-hexanediammonium dodecatungstate, (NH 4 ) 2 (NH 3 (CH 2 ) 6 NH 3 ) 4 [H 2 W 12 O 42 ]Á8H 2 O, contains centrosymmetric [H 2 W 12 O 42 ] 10À anions separated by the ammonium and 1,6-hexanediammonium cations, and water molecules, in a pseudo-layer structure.
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