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NH3 quantum rotators in Hofmann clathrates: intensity and width of rotational transition lines

โœ Scribed by Peter Vorderwisch; Oleg Sobolev; Arnaud Desmedt


Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
201 KB
Volume
350
Category
Article
ISSN
0921-4526

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๐Ÿ“œ SIMILAR VOLUMES


Ammonia tunnelling in Hofmann clathrates
โœ M. Havighorst; M. Prager ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 500 KB

The ammonia groups of the Ni-Ni-Bz(d 6) Hofmann clathrate perform almost free tunnelling rotation in a high symmetry environment, We show that a coherent internal and centre of mass rotation describe the inelastic spectra perfectly. The parameters of the potential surface are consistent with usual s