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NH2 radicals trapped in NH3 single crystals and various polycrystalline ammonia matrices

✍ Scribed by J.P. Michaut; J. Roncin; R. Marx

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
540 KB
Volume
36
Category
Article
ISSN
0009-2614

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✦ Synopsis

GHz radical trapped In xtrious ammonia matrices has been investigtcd

by ESR spectroscopy.

From the study of the toppling tensors of the NH2 mdicril in a sir@ cryst;3 of NH3, and taking into nccount the motions of this radical, it is shown that for a11 these matrices ti~c spectra can be interpreted on the basis oCc~u$ing tensors which give for all cases thz qrnc isotropic tousling constants; a,v = 11.3 G, ati = 24.6 G. Nitrogen and hydrogen cauplin, 0 Tensors for the motionlcas NH2 radica1 arc &SO discussed i'olw~ic 36. ntlrnbcr 5

CWEhIlCAL

PtIYSICS LETTERS

πŸ“œ SIMILAR VOLUMES

Crystal Structures of Ag2ZrF6Β·8NH3 and A
Crystal Structures of Ag2ZrF6Β·8NH3 and Ag2HfF6Β·8NH3 and Their Synthesis by the β€œReactive Fluoride Route” in Liquid Ammonia
✍ Weizhe Meng; Florian Kraus πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 624 KB

## Abstract Starting from the ternary transition‐metal fluorides Ag~3~M~2~F~14~ (M = Zr, Hf) and dry liquid ammonia, [Ag(NH~3~)~4~(μ‐NH~3~)Ag(NH~3~)~3~]ZrF~6~ (1) and [Ag(NH~3~)~4~(μ‐NH~3~)Ag(NH~3~)~3~]HfF~6~ (2) have been prepared as colorless single crystals crystallizing isotypically in the spac