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New β-dihydroagarofuran sesquiterpenoids from Celastrus paniculatus

✍ Scribed by Hong Sang; Hanqing Wang; Yongqiang Tu; Yaozu Chen


Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
364 KB
Volume
29
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

Two new β‐dihydroagarofuran sesquiterpene polyesters were isolated from Celastrus paniculatus. The structures were deduced using various 2D NMR techniques (HH COSY, CH COSY, COLOC, NOESY), NOE difference spectra and mass spectra. The positions of the ester moieties were located by 2D heteronuclear correlated spectra via long‐range coupling, or combined with NOE experiments. Their stereochemical structures were studied and the complete assignments of the ^1^H and ^13^C chemical shifts were made.


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New Dihydroagarofuranoid Sesquiterpenes
✍ Jing-Ru Weng; Ming-Hong Yen 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 German ⚖ 200 KB

## Abstract The six new dihydro‐__β__‐agarofuranoid sesquiterpenes **1**–**6** and three known compounds were isolated from the whole plant of __Celastrus paniculatus.__ The structures including relative configurations were elucidated by means of spectroscopic analyses. Compounds **1**–**6** were e