New ways in determination of the parameters of porous structure of microporous carbonaceous adsorbents
β Scribed by M.M. Dubinin; O. Kadlec
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 252 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0008-6223
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π SIMILAR VOLUMES
A new method has been proposed for calculating apriori the equilibrium characteristics of adsorption of binary mixtures as functions of the structure of carbonaceous microporous adsorbents, and the temperature and adsorbabilities of the mixture components from vapor or liquid. The method uses the re
The general equation of the adsorption isotherm has been derived containing the parameter determining structural heterogeneity related to dimensions of micropores existing in microporous adsorbents. As opposed to the Stoeckii equation, our equation can be used for all microporous adsorbents.
At the basis of the theory of vapor adsorption in the micropores of carbon adsorbents of the most probable slit-like, limited-size type lie the dispersion interactions between the adsorbate and adsorbent atoms as well as between the atoms of the adsorbed substance themselves. As a consequence of com