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New type of transformation of a 1,2,4-triazine ring to pyrazine derivatives

✍ Scribed by S. G. Alekseev; V. N. Charushin; O. N. Chupakhin


Book ID
112384371
Publisher
Springer US
Year
1987
Tongue
English
Weight
94 KB
Volume
23
Category
Article
ISSN
0009-3122

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## Abstract The reaction of 3‐chloro‐6‐phenyl‐1,2,4‐triazine **1a** with carbon nucleophiles **2aο£Ώd** bearing a cyano substituent at a carbanionic center has been studied. In all reactions the formation of the corresponding 3‐aminopyridazines **3aο£Ώd** takes place via ANRORC mechanism involving addi