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New triad alkylation reagent. Cross coupling of indium trialkyls with alkenyl halides

✍ Scribed by Nomura, Ryoki; Miyazaki, Shinichiro; Matsuda, Haruo

Book ID
115480973
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
411 KB
Volume
114
Category
Article
ISSN
0002-7863

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SmI\_JHMPA converts alkyl iodides and bromides to alkyl samarium reagents which can be crosscoupled with primary alkyl icdides and bromides and secondary iodides in the presence of Cu(I) halides or L&CuCl, at room temperature. The alkylation of primary iodides gives good yields of cross-coupling pro