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New total synthesis of equilenin and estrone

✍ Scribed by Andrzej Robert Daniewski; Teresa Kowalczyk-Przewloka

Publisher: Elsevier Science
Year: 1982
Tongue: French
Weight: 201 KB
Volume: 23
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)87355-4

No coin nor oath required. For personal study only.

✦ Synopsis

The coupling of m-methoxystyrene (1) and diazokctonc (2) over copper tartarate gave optically active (L6% cc) cyclopropyl derivative (2) which was converted into compounds 5 or 8 with 22% of optical induction.

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