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New Thermal Rearrangement of 2,4,6-Triarylthio(seleno)pyrylium Salts.

โœ Scribed by B. I. Drevko; E. V. Suchkova; G. A. Baranchikova; V. G. Mandych


Publisher
John Wiley and Sons
Year
2007
Weight
17 KB
Volume
38
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

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THIS BRIEF NOTE is occasioned by recent observations in Germany and the Soviet Union. SchGnleber3 has remarked the thermal conversion of 1-vinylspiro[2.4]hepta-4,6-diene (l-1 to indane at 350ยฐ. In related work, Mironov, et al. 4 --reported the rearrangement of spiro[4.4]nona-1,3-diene to indane at

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We wish to report the thermal behavior of the cis-bicyclo[6.2.0]decenes, I-III. 1 The known' thermal rearrangement of bicyclo[3\*2.0]hepta-2,6-diene to I II III cycloheptatriene is here shown to be extended to the bicyclic systems above which also possess the condensed cyclobutene moiety. It is also