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New Tetrathiapentalene-Derived Charge Transfer Salts with Paramagnetic Transition Metal Complex Anion: κ -(EDDH-TTP) 3 [Cr(phen)(NCS) 4 ]·2CH 2 Cl 2 and κ 21 -(BDH-TTP) 5 [Cr(phen)(NCS) 4 ] 2 ·2CH 2 Cl 2

✍ Scribed by Setifi, Fatima; Ouahab, Lahcène; Golhen, Stéphane; Hernandez, Olivier; Miyazaki, Akira; Enoki, Toshiaki; Toita, Takashi; Yamada, Jun-ichi; Nishikawa, Hiroyuki; Łapiński, Andrzej; Świetlik, Roman


Book ID
127075816
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
253 KB
Volume
41
Category
Article
ISSN
0020-1669

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New Molecular Charge Transfer Salts of B
✍ Scott S. Turner; Peter Day; Thomas Gelbrich; Michael B. Hursthouse 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 341 KB

Two new charge transfer salts of BEDT-TTF, bis (ethylenedithio) tetrathiafulvalene, with thiocyanato-metal complex anions have been synthesized and characterized as (BEDT-TTF) 4 [Fe(NCS) 6 ] ' CH 2 Cl 2 and (BEDT-TTF) 2 [Cr(NCS) 4 (bipym)] ' 0.15H 2 O, where bipym ‫؍‬ 2,2-bipyrimidine. The Fe salt,