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New synthetic ‘tricks’. Direct conversion of nitro compounds to nitriles

✍ Scribed by Fèlix Urpí; Jaume Vilarrasa

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
194 KB
Volume
31
Category
Article
ISSN
0040-4039

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✦ Synopsis

Treatment of primary nitro groups, in CH2Cl2 at 0 "c. with Sn(SPhM. R3P. and DEAD affords quickly and abnost quantitatively the corresponding n&riles. in a combined process of deoxygenation and delrydration. The same restdt can be obtained, although not so rapidly. uing only R3P (2 eqtdv.) ond DEAD (I eqtdv.).

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