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New Synthetic Reactions Using the Reducing Ability of Titanium Tetraiodide

✍ Scribed by Makoto Shimizu


Publisher
John Wiley and Sons
Year
2004
Weight
58 KB
Volume
35
Category
Article
ISSN
0931-7597

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New Synthetic Bromination Procedures for
✍ Jean-Richard Neeser; Laurance D. Hall; Julius A. Balatoni πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons 🌐 German βš– 660 KB

## Abstract In the presence of 2 mol‐equiv. of AcONa, both triglycosylborane **1** and dicyclohexylglycosylborane **2** readily react with bromine chloride generated __in situ__ from bromide and __N__‐chlorosuccinimide (NCS) to give the bromo‐sugar **3** (75 and 60%, resp.). The use of the BH~3~‐TH