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New synthetic reactions: On the regioselectivity chemospecificity of the cyclopentane annelation-cyclopentenone annelation

✍ Scribed by Barry M. Trost; Seizi Kurozumi


Book ID
104234926
Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
197 KB
Volume
15
Category
Article
ISSN
0040-4039

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## Abstract A novel cyclopentenone ring annelation reaction is described. The treatment of the nitro compound **13** with aqueous sodium hydroxide in the presence of a phase‐transfer catalyst furnished **14a** in one step. Similar treatment of **7** led to **8**, the reaction of which with __t__‐Bu