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New synthetic reactions. 12. Dimethylsulfonium 2-oxotetrahydrofuryl-3-ylide as an annelating reagent

โœ Scribed by Trost, Barry M.; Arndt, Henry C.


Book ID
120424817
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
679 KB
Volume
38
Category
Article
ISSN
0022-3263

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## Abstmct: 2-(Tr~mcthylsilylmethyNio~~~tI~yltb~o)~t~~yle~~e-i~3-it~an~i~e(l~, readily prepared by reaction of 2-bis(mrrhylrlldo)~~ti:y&ne-~,3-inda~udi~~9) with trirnethylsilylf~t~~yl~~rcaptat~e(l~~, was sltown to be the synthetic equivalent of alkylldene-thiocarbonyl ytide. Treutment of this compor