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New Synthetic Methodology for Regio- and Stereoselective Synthesis of Oligosaccharides via Sugar Ortho Ester Intermediates

โœ Scribed by Wang, Wei; Kong, Fanzuo


Book ID
120286498
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
51 KB
Volume
63
Category
Article
ISSN
0022-3263

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ChemInform Abstract: New Synthetic Metho
โœ W. WANG; F. KONG ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB ๐Ÿ‘ 2 views

The coupling of acetobromosugars as glycosyl donors with partially protected or unprotected alkyl glycoside acceptors affords ortho esters such as (III) in high yields and excellent regioselectivities. They rearrange as either partially or fully protected compounds with high selectivity to 1โ†’6 and 1