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New Synthesis of Substituted Cyclopentanes via Reactions of γ-Chlorocarbanions with Electron-Deficient Alkenes.

✍ Scribed by Mieczyslaw Makosza; Marek Judka


Publisher
John Wiley and Sons
Year
2004
Weight
174 KB
Volume
35
Category
Article
ISSN
0931-7597

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✍ Mieczysław Mąkosza; Marek Judka 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 German ⚖ 170 KB

## Abstract __γ__‐Chlorocarbanions of proper nucleophilicity, generated from 3‐chloropropyl pentachlorophenyl sulfone (=pentachloro[(3‐chloropropyl)sulfonyl]benzene; **1**; Ar=C~6~Cl~5~), add to electron‐deficient formal imines **3a**–**l** to produce anionic adducts that enter intramolecular subst