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New synthesis of quinolines from lithiated allenes and isothiocyanates

✍ Scribed by L. Brandsma; N. A. Nedolya; R. -J. de Lang; B. A. Trofimov

Book ID: 112537253
Publisher: Springer
Year: 1996
Tongue: English
Weight: 156 KB
Volume: 45
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf01430667

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The products obtained by S-alkylation of the addacts from lithiated allenes and alkyi or aryl isothiocyanates undergo thermal rearrangements with ultimate formation of derivatives of 2,3-dihydropyridine, cyclobutanopyrrolineand quinoline, depending on the structure of the isothiocyanate. In some rea

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Example of the synthesis of quinolines by the reaction of lithiated allenes with phenyl isothiocyanate: 2-Methylthio-4-cyclohexylquinoline

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