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New synthesis of glycerol carbonate from glycerol using sulfur-assisted carbonylation with carbon monoxide

✍ Scribed by Takumi Mizuno; Takeo Nakai; Masatoshi Mihara

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
81 KB
Volume
21
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

The glycerol carbonate synthesis from glycerol, which is an inevitable by‐product of biodiesel production, was established. By combined sulfur‐assisted carbonylation of glycerol under 1.0 MPa of carbon monoxide at 80°C in DMF with oxidation by copper bromide(II), a facile synthetic method for glycerol carbonate in good yield was developed. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:99–102, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20583

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