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New Synthesis of Functionalized Chromium Carbene Complexes Using Zinc Organometallics

โœ Scribed by Stadtmueller, Heinz; Knochel, Paul

Book ID
115442812
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
479 KB
Volume
14
Category
Article
ISSN
0276-7333

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The new C2-symmetrical diphosphines 1--4 of potential interest for asymmetric catalysis were prepared in protected form by a convergent synthesis based on the use of readily available (S,S)-l,2-cyciohexanedicarboxylic acid 8 and the phosphorus reagent (Et2N)2PLi.BH 3. (~) 1997 Elsevier Science Ltd C