New synthesis of 28- and 30- crown-formazans and Bis formazans
β Scribed by Ashraf A. Abbas
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 375 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0040-4020
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β¦ Synopsis
The macrocyclic cyano crown formazans 3a-e and cyano crown formazans with two formazyl moieties 4a-c were prepared by the azo coupling of the appropriate bis diazonittm salts 2a-c with cyanoacetic acid m different meditun. The Bis macrocyclic crown formazan 9 was prepared by condensation of 1.3-diaminopropane with the 16-oxo crown formazan 8. The latter was prepared by ozonolysis of 16-methylene crown formazan 3a.
π SIMILAR VOLUMES
## Absfmk The macmcyclic crown-formamas 7ac. 121-g were prepared by the azc coupling of the appropriate bisdiazoaium salts 4a-c with pyruvic acid and a&ruvic acids 8~. The ready accessability of the latters e&m an easy access towards l,$-symnWically disubstihW4i-3-arylformazam e.g. 1Oa-g as well a