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New syntheses of functional arenesulfonyl azides

✍ Scribed by Ulrich, Henri; Stuber, F. A.; Tucker, B.; Sayigh, A. A. R.

Book ID
118007176
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
457 KB
Volume
40
Category
Article
ISSN
0022-3263

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Electrophilic additions of arenesulfonyl azides (i.e., TsN3 and NsN3) to 3-ethyl-1-azabicycio-[1.1.0]butane (1) in CDCI3 at 80"C has been observed to result in the formation of oligomeric products. The mechanism of these reactions probably involves the formation of a carbocationic intermediate, i.e.