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New Structural Motifs in the Aggregation of Neutral Gold(I) Complexes: Structures and Luminescence from (Alkyl isocyanide)AuCN

✍ Scribed by White-Morris, Rochelle L.; Stender, Matthias; Tinti, Dino S.; Balch, Alan L.; Rios, Daniel; Attar, Saeed


Book ID
121290940
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
189 KB
Volume
42
Category
Article
ISSN
0020-1669

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Treatment of the (isocyanide)gold(I) species LAuCl (L t BuNC, 2,6-Me 2 C 6 H 3 NC) with 4-mercaptobenzoic acid in the presence of NaOMe yields the complexes [Au(4-SC 6 H 4 CO 2 H)L] in good yield. Reaction of LAuCl with 2-HSQn (Qn quinoline) and 2-HSPy (Py pyridine) under the same conditions provide