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New strategy for the synthesis of the taxane diterpenes: Formation of the A-ring and introduction of the C-1 hydroxyl group

โœ Scribed by Philip Magnus; John Booth; Nicholas Magnus; James Tarrant; Stephen Thom; Feroze Ujjainwalla


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
213 KB
Volume
36
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


A synthetic approach to taxane diterpene
โœ Yasuo Ohtsuka; Takeshi Oishi ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 253 KB

Bicyclo[5.3.l]undecenone 2 corresponding to A and B rings in taxane diterpenes was synthesized. The eight-membered ring was constructed by a baseinduced intramolecular cyclization of twelve-membered lactam sulfoxides 15. 204 lja,b ya,bl,b2 isomer NC-S J K \*H,6 5 4 9 07 / 11' 1 3 10 -. 2 0 H R NHMe