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New stable reagents for the nucleophilic trifluoromethylation. Part 2: Trifluoromethylation with silylated hemiaminals of trifluoroacetaldehyde

✍ Scribed by T Billard; B.R Langlois*; G Blond

Book ID: 104211102
Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 102 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)01552-5

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✦ Synopsis

New reagents for the nucleophilic trifluoromethylation have been easily synthesized from fluoral hemiketal. They provide silylated trifluoromethylcarbinol from non-enolizable carbonyl compounds.

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