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New Stable Germylenes, Stannylenes, and Related Compounds. 1. Stable Germanium(II) and Tin(II) Compounds M(OCH 2 CH 2 NMe 2 ) 2 (M = Ge, Sn) with Intramolecular Coordination Metal−Nitrogen Bonds. Synthesis and Structure

✍ Scribed by Zemlyansky, Nikolay N.; Borisova, Irina V.; Kuznetsova, Marianna G.; Khrustalev, Victor N.; Ustynyuk, Yuri A.; Nechaev, Mikhael S.; Lunin, Valery V.; Barrau, Jacques; Rima, Ghassoub

Book ID: 125942390
Publisher: American Chemical Society
Year: 2003
Tongue: English
Weight: 228 KB
Volume: 22
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om020719a

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## Abstract New stable amidogermanium(II) and ‐tin(II) chlorides R~2~NE^14^Cl [E^14^ = Ge, R = Et (**1**), E^14^ = Sn, R = Me (**2**)] have been synthesized and their crystal structures have been determined by X‐ray diffraction analysis. Both **1** and **2** are dimers formed via the two intermol