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New stable 1,2-dioxetane and steric factors in the oxidation of singlet oxygen

โœ Scribed by G. A. Tolstikov; V. P. Kazakov; G. L. Sharipov; A. I. Voloshin; S. S. Ostakhov; B. M. Lerman; T. A. Belogaeva

Book ID
112445203
Publisher
Springer
Year
1984
Tongue
English
Weight
77 KB
Volume
33
Category
Article
ISSN
1573-9171

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โœ Waldemar Adam; Hector Rebollo ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 227 KB

Tetraphenylporphyrin-sensitized photooxygenation of cycloheptatriene afforded the 1,2-dioxetane (3 ) in 9% yield, %% thus completing the set of possible cycloa dition products; the 1,2-dioxetane (&$ 1s the precursor to the benzaldehyde product, but not the (2+6)-cycloadduct (&).