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New seven-coordinate mixed triphenylphosphine, arsine and antimony complexes of molybdenum(II) and tungsten(II)

✍ Scribed by Paul K. Baker; Stuart G. Fraser

Publisher
Springer
Year
1986
Tongue
English
Weight
216 KB
Volume
11
Category
Article
ISSN
0340-4285

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πŸ“œ SIMILAR VOLUMES

Seven-coordinate complexes of molybdenum
Seven-coordinate complexes of molybdenum(II) and tungsten(II) containing pyrazole as a ligand
✍ Paul K. Baker; Marit van Kampen; Christina Roos; Julia Spaeth πŸ“‚ Article πŸ“… 1994 πŸ› Springer 🌐 English βš– 352 KB

Equimolar quantities of [MI2(CO)3(NCMe)2 ] (M = Mo or W) and C3H4N2 (pyrazole) react in CH2C12 at room temperature to give the iodo-bridged dimers [M(#-I)(CO)3(C:~H~N2)]2 (I) and (2). Two equivalents of C3H4N 2 react with [MIz(CO)a(NCMe)2] (M = Mo or W) to give the bis(pyrazole) complexes [MIz(CO)3(