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New sensitizing relay compounds for H2 production

✍ Scribed by R. Bauer; C. Königstein

Book ID
103729615
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
385 KB
Volume
18
Category
Article
ISSN
0360-3199

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As expected, flash vacuum pyrolysis of dichloroglyoxime 13 leads to smooth formation of the well-known cyanogen di-N-oxide 14, which is stable up to -45"C.1131 A special feature of this series is that photoexcitation of 14 (1 = 254 nm) does not lead to the isocyanate 15, but to nitrosyl cyanide 18.I