Condensation of sodium cyanatc with haloalkyl(meth)acrybttes under sppropriete phase @an&r catalytic conditions led to the setective fernration of monomers containing isqauate. u&am&, urea of isccyanurate group. The selectivity of these new syntheses of such derivatives depends on the tempexature a
✦ LIBER ✦
New selective syntheses of (meth)acrylic monomers: Isocyanates, isocyanurates, carbamates and ureas derivatives
✍ Scribed by Christine Dubosclard-Gottardi; Paul Caubère; Yves Fort
- Book ID
- 103405853
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 767 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0040-4020
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The two new functional monomers, UMAI and UDMAI, having amide groups were prepared on reaction of methacryloyl isocyanate (MAI) with urea at low temperature. The monomers thus obtained were characterized by elemental analysis, as well as infrared, ultraviolet, 1 H and 13 C-NMR (nuclear magnetic reso