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New Routes to High Nuclearity Clusters: Fluoride-Based Octametallic and Tridecametallic Clusters of Manganese

✍ Scribed by Jones, Leigh F.; Brechin, Euan K.; Collison, David; Raftery, James; Teat, Simon J.


Book ID
126057750
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
104 KB
Volume
42
Category
Article
ISSN
0020-1669

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## Abstract The syntheses, structures and magnetic properties of three new Mn^III^ clusters, [Mn~26~O~17~(OH)~8~(OMe)~4~F~10~(bta)~22~(MeOH)~14~(H~2~O)~2~] (1), [Mn~10~O~6~(OH)~2~(bta)~8~(py)~8~F~8~] (2) and [NHEt~3~]~2~[Mn~3~O(bta)~6~F~3~] (3), are reported (bta=anion of benzotriazole), thereby de