The complex [Pt(Cl 3 terpy)Cl]PF 6 has been prepared from cis-[Pt(dimethylsulfoxide) 2 Cl 2 ] and 4,4%,4¦-trichloro-2,2%:6%,2¦-terpyridine (Cl 3 terpy). The complex [Pt(Clterpy)Cl]Cl has been prepared from cis-[Pt (1,5-cyclooctadiene)Cl 2 ] and 4%-chloro-2,2%:6%,2¦terpyridine (Clterpy). Complexes ha
New routes for the synthesis of chloro(diethylenetriamine) platinum(II) chloride and chloro(2,2′ : 6′,2″-terpyridine) platinum(II) chloride dihydrate
✍ Scribed by Giuliano Annibale; Matilde Brandolisio; Bruno Pitteri
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 227 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0277-5387
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The addition of a solution of terpy (2,2%;6%,2¦-terpyridine) to a solution of cis-[PtCl 2 (dmso) 2 ] (dmso, dimethylsulfoxide) in acetone, at 25°C, brought to the formation of [PtCl(terpy)][PtCl 3 (dmso)] (1), as a high yield crystalline red powder, within 12 h. Single crystals of 1 suitable for X-r
A family of bis-[4Ј-Azido-2,2Ј:6Ј,2Љ-terpyridine platinum(II)] complexes with linear linkers of varying length have been synthesized. They have been designed to bis-intercalate into two DNA duplexes in close proximity, the azido groups allowing the sites of intercalation to be photoaffinity labeled.