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New route to 11-oxygenated steroids

✍ Scribed by Stork, Gilbert; Clark, G.; Shiner, Christopher S.

Book ID: 126146312
Publisher: American Chemical Society
Year: 1981
Tongue: English
Weight: 236 KB
Volume: 103
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00406a050

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We wish to report various novel reactions and intermediates which permit the development of efficient total syntheses of a wide variety of 11-oxygenated steroids from intermediates which have previously been converted to estrone, 1,2 equilenin, 1,2 equilin,3 and other steroid hormones.