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New ring-opening polymerization via a .pi.-allyl complex. 1. Polymerization of diethyl 2-vinylcyclopropane-1,1-dicarboxylate catalyzed by a palladium(0) complex

✍ Scribed by Suzuki, Masato; Sawada, Shuji; Saegusa, Takeo

Book ID: 127003339
Publisher: American Chemical Society
Year: 1989
Tongue: English
Weight: 414 KB
Volume: 22
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma00193a091

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Palladium(ii) complexes with N-donor ligands have recently attracted significant interest as a result of their utility as alkene polymerization catalysis. [1] Strained cyclic olefins such as cyclopropenes and norbornadiene also undergo addition polymerization catalyzed by palladium(ii) complexes. [2