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New rearrangement in biphenyl series

✍ Scribed by F. M. Stoyanovich; G. B. Chermanova; Ya. L. Gol'dfarb


Book ID
112497169
Publisher
Springer
Year
1973
Tongue
English
Weight
164 KB
Volume
22
Category
Article
ISSN
1573-9171

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In an aqueous alcohol solution of hydrogen chloride 1-(2-propionylphenyl)amino-2-alkoxy-2-methyl-3-indolinone undergoes rearrangement to 2-(2-acetylcarbonyl)phenyl-3-ethylindazole. The structure of the rearrangement product was investigated by x-ray diffraction analysis.

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Some time ago (1) we reported on dicarbonium ions of the triarylmethyl type in which the sites of ionization were attached ortho, meta or para on a single benzene ring. We now wish to record results (2) on the spectra and pK R++ '6 of dicarbonium ions in which the ionization sites are separated by t