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New rearranged products from the methylation of 13-oxobaccatin III

✍ Scribed by Vittorio Pinciroli; Walter Ceccarelli; Domeico Fusar-Bassini; Maria Menichincheri; Nicola Mongelli; Ermes Vanotti

Book ID
104258741
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
292 KB
Volume
37
Category
Article
ISSN
0040-4039

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✦ Synopsis

Abstraef. Treatmem of 7-triethylsilyl-13-oxobaccatin III (1) with sodium hydride and methyl iodide gave the methylated ten-membered rin~ compound 2 that rearranged, via intramolecular aldol eundensation, to unsaturated decalin ring system (3, 4,5 ). These molecules were characterized by ID

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