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New reagents for the iodobromination of alkenes

โœ Scribed by N. V. Zyk; V. S. Tyurin; A. V. Belov; N. S. Zefirov

Book ID
105602853
Publisher
Springer
Year
1997
Tongue
English
Weight
84 KB
Volume
46
Category
Article
ISSN
1573-9171

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A new promising in situ generated hydroborating agent, isopinocampheylbromoborane (IpcBHBr), achieves the asymmetric hydroboration of representative prochiral alkenes in pentane at lower temperatures, even at -78 ยฐC, than has been possible with isopinocampheylborane (IpcBH2) and isopinocampheylchlor