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New pyridine carboxamide ligands and their complexation to copper(ii). X-Ray crystal structures of mono-, di, tri- and tetranuclear copper complexes

โœ Scribed by Jain, Sneh L.; Bhattacharyya, Pravat; Milton, Heather L.; Slawin, Alexandra M. Z.; Crayston, Joe A.; Woollins, J. Derek


Book ID
120609266
Publisher
Royal Society of Chemistry
Year
2004
Tongue
English
Weight
430 KB
Volume
6
Category
Article
ISSN
1477-9226

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Bis(terdentate) Pyrazole/Pyridine Ligand
โœ Akhilesh Kumar Singh; Jarl Ivar van der Vlugt; Serhiy Demeshko; Sebastian Decher ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 450 KB ๐Ÿ‘ 2 views

## Abstract A new binucleating bis(terdentate) ligand, 3,5โ€[3โ€bis(2โ€pyridyl)pyrazoleโ€1โ€ylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (ฮผโ€pyrazolato)(ฮผโ€hydroxido)โ€bridged binuclear and tetranuclear complexes [L^2^Cu~2~(ฮผโ€OH)(ClO~