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New protective groups for peptide synthesis--III the maq ester group mild reductive cleavage of 2-acyloxymethyleneanthraquinones

✍ Scribed by D.S. Kemp; James Reczek

Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
253 KB
Volume
18
Category
Article
ISSN
0040-4039

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✦ Synopsis

As part of our long range program for developing a synthesis,' we wish to report the preparation and uses Maq esters. Esters of the 2-oxymethyleneanthraquinone tional operations of peptide synthesis but are cleaved mild reducing agents. compatible set of new reagents for peptide of a new carboxyl protective group, the (Maq) function are stable to the convenin high yield by a variety of selective, B 9 Moq Ester ! 03f4/\OCR 0

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A New Reagent for the Cleavage of NPS-Am
A New Reagent for the Cleavage of NPS-Amino Protecting Groups in Peptide Synthesis
✍ Marcel Juillerat; J. Pierre Bargetzi 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 German ⚖ 840 KB

## Abstract The value of several reagents capable of removing quantitatively the α‐amino protecting group of NPS‐aminoacyl‐ or peptidyl‐derivatives is assessed, by comparison with the reagents currently used, __i.e.__ hydrogen chloride, RS^–^‐nucleophiles or alkyl thioamides, especially with regard