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New possibilities of overlapping Raman band resolution by methods of CARS spectroscopy

✍ Scribed by A. I. Fishman; S. F. Mironov


Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
649 KB
Volume
25
Category
Article
ISSN
0377-0486

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✦ Synopsis


Abstract

New possibilities for the resolution of Raman bands, provided by polarization‐sensitive CARS in combination with a phase‐mismatching technique, are presented. The use of this combination of techniques allows one to achieve the most informative spectra and resolve the complex structure of inhomogeneously broadened contours. The variation of the resonant/non‐resonant ratio using a phase‐mismatching technique and the special possibilities of polarization CARS spectroscopy in lineshape formation are used. The results of an investigation of a cyclohexane and naphthalene mixture and of n‐pentane by polarization CARS in combination with a phase‐mismatching technique are presented.


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