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New polymorphs of RuIIIP3O9: Cyclo-hexaphosphate Ru2P6O18 and metaphosphate Ru(PO3)3 with a novel structure

✍ Scribed by Hiroshi Fukuoka; Hideo Imoto; Taro Saito


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
818 KB
Volume
119
Category
Article
ISSN
0022-4596

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Synthesis and crystal structure of a new
✍ O. Amri; S. Abid; M. Rzaigui 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 220 KB

Single crystals of (4-ClC 7 H 6 NH 3 ) 9 [Nd(P 6 O 18 ) 2 ].9H 2 O were synthesized in aqueous solution. This compound crystallizes in a triclinic P1 unit-cell, with a = 14.898( 6), b = 18.049( 7), c = 20.695(6)Å, α = 102.04(3), β = 100.49(3), γ = 98.82(3)°, V = 5245(4) 3 Å and Z = 2. The crystal s