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New phototautomerizing systems: non-symmetric derivatives of [2,2′-bipyridyl]-3,3′-diol

✍ Scribed by Paweł Borowicz; Anna Grabowska; Andrzej Leś; Łukasz Kaczmarek; Bogdan Zagrodzki

Book ID
108312495
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
228 KB
Volume
291
Category
Article
ISSN
0009-2614

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## Thermochemical and mechanistic aspects of tautomerization resulting from proton transfer in [2,2'-bipyridyl]-3,3'-diol have been investigated by ab initio computations. From a classical point of view, complete characterization of energy minima and first-order saddle points indicates that proton

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The complexation behaviour of 2,2Ј-bipyridyl-3,3Ј-diol and 2,2Ј-bipyridyl-3-ol, BP(OH) 2 and BPOH, with various heavy and transition metal ions has been investigated in aqueous, alcoholic, and acetonitrile solutions. Whereas the complexes with paramagnetic ions and Hg II are non-fluorescent, Zn II a