✦ LIBER ✦

New Photorearrangements of 2-Cyclopentenones. The Genesis and Fate of Cyclopropylcarbinyl Biradical Intermediates

✍ Scribed by Paquette, Leo A.; Zhao, Zhong; Gallou, Fabrice; Liu, Jian

Book ID: 127394604
Publisher: American Chemical Society
Year: 2000
Tongue: English
Weight: 46 KB
Volume: 122
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja994081e

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

ChemInform Abstract: New Photorearrangem

ChemInform Abstract: New Photorearrangements of 2-Cyclopentenones. The Genesis and Fate of Cyclopropylcarbinyl Biradical Intermediates.

✍ Leo A. Paquette; Zhong Zhao; Fabrice Gallou; Jian Liu 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB

Independent generation of triplet 1,4-bi

Independent generation of triplet 1,4-biradical intermediates implicated in the photochemical cycloaddition reaction between 2-cyclopentenone and acrylonitrile

✍ Paul Krug; Andreas Rudolph; Alan C. Weedon 📂 Article 📅 1993 🏛 Elsevier Science 🌐 French ⚖ 332 KB

CHN 2- : A Biradical Anion and a Potenti

CHN 2- : A Biradical Anion and a Potentially New Type of Reactive Intermediate

✍ Gordon, M. S.; Kass, S. R. 📂 Article 📅 1997 🏛 American Chemical Society 🌐 English ⚖ 12 KB

The Photorearrangements of a Naphthobarr

The Photorearrangements of a Naphthobarrelene-like System. Dependence on excited-state spin multiplicity and electronic configuration, and evidence for biradical intermediates. Preliminary communication

✍ Martin Demuth; Christopher O. Bender; Slivia E. Braslavsky; Helmut Görner; Ulric 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 German ⚖ 315 KB 👁 1 views

8-Benzoyl-9-deuterio-naphtho [ de-2.3.4]bicyclo [3.2.2]nona-2,6,8-triene (1) rearranged quantitatively in a photochemical di-z-methane-type process to 2-, 6-, and 9-deuteriated 1 -benzoyl-naphtho [ de-2.3.4]tricyclo [4.3.0.0239]nona-2, 6-diene (8a-c). The phenylhydroxymethyl analogue 2 underwent a s

Biradical Intermediate in the [2 + 2] Ph

Biradical Intermediate in the [2 + 2] Photocycloaddition of Dienes and Alkenes to [60]Fullerene

✍ Hatzimarinaki, Maria; Roubelakis, Manolis M.; Orfanopoulos, Michael 📂 Article 📅 2005 🏛 American Chemical Society 🌐 English ⚖ 51 KB

An MC-SCF/MP2 Study of the Photochemistr

An MC-SCF/MP2 Study of the Photochemistry of 2,3-Diazabicyclo[2.2.1]hept-2-ene: Production and Fate of Diazenyl and Hydrazonyl Biradicals

✍ Yamamoto, Naoko; Olivucci, Massimo; Celani, Paolo; Bernardi, Fernando; Robb, Mic 📂 Article 📅 1998 🏛 American Chemical Society 🌐 English ⚖ 282 KB