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New Phosphorylated Derivatives of Piperidine and Pyrrolidine

✍ Scribed by Şener, Şadiye ;Mete, Ahmet

Book ID
126570193
Publisher
Taylor and Francis Group
Year
1997
Tongue
English
Weight
203 KB
Volume
27
Category
Article
ISSN
0039-7911

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✍ Ramaiah Kumareswaran; Thiagarajan Balasubramanian; Alfred Hassner 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 102 KB

The additions of lithiated allylsulfone carbanion to chiral N-sulfinylimines were found to proceed with good to excellent selectivity. The resulting intermediates 4a-d after transformation to dienylamides 7a-d and 16a-d, were converted to functionalized enantiopure piperidines and pyrrolines, respec