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New perspectives in the chemistry of nitrile oxides

โœ Scribed by G.Lo Vecchio; F. Foti; G. Grassi; F. Risitano


Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
82 KB
Volume
18
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


New aspects of nitrile oxides chemistry
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Fkactivity of nitrile oxides (1) towards both dimerization and cycloaddition with dipdarophiles can be inhibited by catalytic amount of tris-(4\_bromophenyl)-aminium hexachloroantimonate and dsequently restored.

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Nitrile oxides in medicinal chemistry-2.
โœ Marco De Amici; Carlo De Micheli; Valeria Misani ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 821 KB

The cycloaddition of bromonitrile oxide to monosubstituted ole,Gs has a high regioselectivity yielding 3-bromo-S-substhuted isoxazolines contaminated by minor amounts (4-9%) of the I-substituted isomer. The adducts of bromonitrile oxide to ally1 a3lcohol and N-protected allylamine were employed as h

New perspectives in the chemistry of 1-a
โœ Luisa Garanti; Gaetano Zecchi ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 125 KB

Thermal decomposltlon of 1-azidohydrazones iI] results in tricyclic products [III], probably arising from nitrene intermediates through an mtramolecular cycloaddition to the ethylemc bond. Despite l-azldohydrazones may be seen as potential intermediates in heterocyclic syntheses,

New conditions for the generation of nit
โœ Nathalie Maugein; Alain Wagner; Charles Mioskowski ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 214 KB

Original dehydrating reagents for the efficient formation of nitrile oxides from primary nitro compounds are reported. Burgess salt, DAST, acetic anhydride and oxalyl chloride were shown to be useful reagents to perform this transformation.