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New pentanuclear mixed valence Co(ii)???Co(iii) complexes of ???short??? salen homologuesElectronic supplementary information (ESI) available: Table S1 (selected interatomic distances and angles for H2salNO2ben, [Co5(??3-OH)2(salNO2ben)4]I??CH3CO and [Co5(??3-OH)2(salClben)4]I??2DMF??CH2Cl2) and the expression for the magnetic susceptibility. See http://www.rsc.org/suppdata/dt/b2/b206221f/

✍ Scribed by Chiari, Brunetto; Cinti, Antonio; Crispu, Ornella; Demartin, Francesco; Pasini, Alessandro; Piovesana, Olivo

Book ID: 121293822
Publisher: The Royal Society of Chemistry
Year: 2002
Tongue: English
Weight: 167 KB
Volume: 24
Category: Article
ISSN: 1472-7773
DOI: 10.1039/B206221F

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Aerial oxidation of primary alcohols and

Aerial oxidation of primary alcohols and amines catalyzed by Cu(ii) complexes of 2,2?-selenobis(4,6-di-tert-butylphenol) providing [O,Se,O]-donor atomsElectronic supplementary information (ESI) available: Molecular structures of H2LSe (Fig. S1), complex 2 [CuLSe(Et2NH)] (Fig. S2), complex 5 [(LSe)2(HLSe)Cu3(�2-OH)(CH3CN)] (Fig. S3) and EPR spectra for complexes 1, 4 and 5 with their simulations (Figs. S4?S7). Tables S1 and S2 list the bond lengths and angles for H2LSe and complex 5, respectively. See http://www.rsc.org/suppdata/dt/b4/b403953j/

✍ Paine, Tapan K.; Weyherm�ller, Thomas; Wieghardt, Karl; Chaudhuri, Phalguni 📂 Article 📅 2004 🏛 Royal Society of Chemistry 🌐 English ⚖ 485 KB

Physical stability vs. chemical lability

Physical stability vs. chemical lability in microporous metal coordination polymers: a comparison of [Cu(OH)(INA)]n and [Cu(INA)2]n: INA = 1,4-(NC5H4CO2)Electronic supplementary information (ESI) available: 1. Structure determination summaries for compounds 1–3. 2. Powder X-ray diffraction patterns: (a) for 1 and (b) for 2 after prolonged heating at different temperatures, establishing framework stabilities and (c) showing transformation of polymer 2 to the molecular compound 3, after 12 h in H2O. Fig. S1: copper coordination environments in compounds 1–3. See http://www.rsc.org/suppdata/cc/b2/b201501n/

✍ Lin, Candy Z-J.; Chui, Stephen S-Y.; Lo, Samuel M-F.; Shek, Fanny L-Y.; Wu, Ming 📂 Article 📅 2002 🏛 Royal Society of Chemistry 🌐 English ⚖ 149 KB

Activity coefficients in mixed electroly

Activity coefficients in mixed electrolyte solutionsElectronic supplementary information (ESI) available: (Part A) 1. Apparatus and reagents. 2. Modus operandi. 3. Ion selectivity and water-induced ion selectivity. 4. Tests for ion selectivity (Tables S1–S5). 5. Less demanding checks. 6. Mixed electrolytes with (and without) ions in common. 7. Revised activity coefficients of [Co(en)3][Co(CN)6] in water at 298.15 K (Table S6). 8. Activity coefficients of reference mixed solutions (Tables S7–S15). 9. Activity coefficients of trace electrolytes in supporting electrolytes of variable concentration. (Tables S16–S24). 10. Ion hydration effects. (Part B). The IPBE algorithm: how to use the computation program; the source program IPBE. See http://www.rsc.org/suppdata/cp/b3/b311624g/

✍ Malatesta, Francesco; Fagiolini, Chiara; Franceschi, Roberto 📂 Article 📅 2004 🏛 Royal Society of Chemistry 🌐 English ⚖ 181 KB