New Organic Nonlinear Optical Polyene Crystals and Their Unusual Phase Transitions

✍ Scribed by O-P. Kwon; S.-J. Kwon; M. Jazbinsek; A. Choubey; V. Gramlich; P. Günter

• Publisher: John Wiley and Sons
• Year: 2007
• Tongue: English
• Weight: 540 KB
• Volume: 17
• Category: Article
• ISSN: 1616-301X
• DOI: 10.1002/adfm.200600494

✦ Synopsis

Abstract

A series of new nonlinear optical chromophores based on configurationally locked polyenes (CLPs) with chiral pyrrolidine donors are synthesized. All CLP derivatives exhibit high thermal stability with decomposition temperatures T~d~ at least >  270 °C. Acentric single crystals of enantiopure D‐ and L‐prolinol‐based chromophores with a monoclinic space group __P__2~1~ exhibit a macroscopic second‐order nonlinearity that is twice as large than that of analogous dimethylamino‐based crystal. This is attributed to a strong hydrogen‐bonded polar polymer‐like chain built by these molecules, which is aligned along the polar crystallographic b‐axis. Five α‐phase CLP crystals with different donors grown from solution exhibit a reversible or irreversible thermally induced structural phase transition to a β‐phase. These phase transitions are unusual, changing the crystal symmetry from higher to lower at increasing temperatures, for example, from centrosymmetric to non‐centrosymmetric, enhancing their macroscopic second‐order nonlinear optical properties.