New non-heme iron model compounds as catalysts in the oxidation of olefins
β Scribed by Carlos Lopez de Laorden; Michael Merz; Peter Comba
- Book ID
- 108403882
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 206 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0162-0134
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π SIMILAR VOLUMES
The non-heme iron complex, Fe(TPAA = tris-[N-(2-pyridylmethyl)-2-aminoethyl]amine)(ClO 4 ) 2 , is a bad catalyst for the epoxidation of alkenes such as cyclooctene, cyclohexene and cis-stilbene and for the hydroxylation of alkanes such as adamantane by H 2 O 2 , when compared to the iron porphyrin F
## Abstract Taking the regioβ and chemoselectivities of our iron complex precursors with pyridine core in aerobic oxidations into account, we envisioned a more effective influence on catalytic properties by the introduction of different substituents in 4βposition of the pyridine moiety. The synthes